There were several trigger guard shapes. The oldest had an almost oval trigger guard. Then they moved to one that was more circular, and finally, they added a squared front edge to it, that looks like the current "B" models.
Transitional models are just that -- ones that begin incorporating the modern "B" features but still don't use the current firing pin block.
As noted previously, front sights differ, as does the width of the rear dovetail. (The oldest pre-B sights don't work on Bs, but some transitional pre-B have the same dovetail as current B.) It's a crap shoot.
The same is true of the hammer design, most with a half-cock notch, but a few without. Some are too wide to use the current Kadet Kit (I had one of those. It also didn't have the half-cock notch.)
Guide rods changed, with the earliest ones being metal, changing to hard plastic. (The Compacts use a different type of plastic.)
I think the ambi-slide release on the 85Bs and 85s are sometimes different, too. CZ will update the slide stop on an older 85 free.
Safety designs (cosmetic and internal) changed, as did the slide stop and the interior dimensions of the mag channel in the grip.
There's no clear-cut date that different features were worked in -- or none that we've been able to discern. CZ had a knack for making up a lot of parts at one time, serial numbering them later, and then date-stamping them still later, when they left the factory. Serial numbers and dates don't run consistently, nor do specific features. About all that can be said is that the transitional guns are newer than the older, more classic pre-Bs. The more "B" features found, the newer it is likely to be.
As for manuals -- unless you can get someone to photocopy or scan one of the old pre-B manuals, you're out of luck. However, field stripping is exactly the same for the B and pre-B models, so you can download a new manual from the CZ-USA website and print it out.
The most interesting pre-Bs are those from Germany which were modified by a firm there name Frankonia. Very nice guns with a lot of custom features.