Since you've got a fully supported chamber, the chances of a kaboom seem pretty slim. I
understand your discomfort, but also think CZ wouldn't be too cavalier about the problem if they felt there was any real personal danger (or, more important, corporate liability) involved.
Seems like the problem you mention would be present anytime you have an undersprung gun, and that isn't isn't usually the case. In those cases, the slide just sling the brass farther, and batters the slide stop more noticeably.
I wonder if your FP spring is giving up the ghost?
I would think, too, that if the barrel was unlocking BEFORE the bullet has left the barrel, the point of impact would be changing -- it would almost have to be higher than expected, wouldn't it? (Since the barrel was already rocking back...) Have you noticed that, as well?
We've already found, in other message chains, that CZ-75B springs can be adapated to CZ-40Bs, if a couple of coils are cut from the spring. (3-4?). I wonder if the same process will work with the CZ-100? I also wonder if the firing pin spring will work in the CZ-100, too? (Or maybe you can just order a new one from CZ.) Might be worth ordering an extra-strength CZ-75B spring to find out.