Lots of answers to this question on the RFC thread. Shims mostly depend on the ammo you're using - some rims are thicker than others. More important is the quality of the ammo, shims are not likely to improve cra* ammo's accuracy. If you're using 'Really Pricey' ammo, you might notice an improvement. It's a cheap mod, and if it doesn't help you can easily reverse it.
Also, as said on the RFC thread, the VMTR only has a Match Chamber, the action is not different vs Varmint or American, etc.