As long as the sides of the hammer can not contact the sides of the slide channel, I wouldn't worry about it. Can you use finger pressure to center the hammer in the notch? If so it is probably caused by there being a little slop in the hammer pin or some side to side play in the hammer. If this is the case a new hammer pin may help, if it is slightly larger in diameter than yours.
Almost forgot to mention, the decocker versions of the CZ use only one hammer hook, so with the aluminum frame being a little loser fit than the steel one, combined with the single hammer hook, that would probably be the cause of the canted hammer. My hammer fit on the Rami alloy frame that I own is way sloppier than any of the steel frame CZ's that I own. It isnt an issue as far as reliability or shootability goes, just a little annoying and it kept me from putting a competition hammer in the Rami. I figured with that much side to side play I didnt want to put a hammer in it with that short of hammer hooks.